In Pursuit of an Ideal Carbon–Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins
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SYNLETT 2009, No. 6, pp 0853–0885xx.xx.2009 Advanced online publication: 16.03.2009 DOI: 10.1055/s-0028-1088213; Art ID: A50608ST © Georg Thieme Verlag Stuttgart · New York Abstract: Attempts to introduce the highly versatile vinyl group into other organic molecules in a chemo-, regio-, and stereoselective fashion via catalytic activation of ethylene provided challenging opportunities to explore new ligand and salt effects in homogeneous catalysis. This review provides a personal account of the development of enantioselective reactions involving ethylene.
منابع مشابه
Asymmetric hydrovinylation reaction.
Carbon-carbon bond-forming reactions are among the most important types of bond constructions in organic chemistry. Yet, the paucity of methods for the stereoselective incorporation of abundantly available carbon feedstocks such as CO, CO2, HCN, or simple olefins to prochiral substrates is one of the major limitations in this area.1 Ideally, from a manufacturing perspective, these reactions sho...
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تاریخ انتشار 2009